Abstract Details - Morris Jones

Inhibition Mechanism of Uranyl Reduction Induced by Calcium-Carbonato Complexes
Presenter Morris Jones
Presentation Type Poster
Full Author List

Morris Jones, John Bargar, Scott Fendorf

Affiliations

Stanford University

Abstract

Uranium mobility in the subsurface is controlled by the redox state and chemical speciation, generally as minimally soluble U(IV) or soluble U(VI) species.  In the presence of even low carbonate concentrations the uranyl-carbonato complex quickly becomes the dominant aqueous species; they are, in fact, the primary aqueous species in most groundwaters.  Calcium in groundwater leads to ternary calcium-uranyl-carbonato complexes that limit the rate and extent of U(VI) reduction.  This decrease in reduction rate has been attributed to surface processes, thermodynamic limitations, and kinetic factors. Here we present a new mechanism for the inhibition of ferrous iron reduction of uranyl-carbonato species in the presence of calcium. A series of experiments under variable Ca conditions were preformed to determine the role of Ca in the inhibition of U reduction by ferrous iron. Calcium ions in the

Ca2UO2(CO3)3  complex sterically prevent the interaction of Fe(II) with U(VI), in turn preventing the Fe(II)-U(VI) distance required for electron transfer. The mechanism described here helps to predict U redox transformations in suboxic environments and clarifies the role of Ca in the fate and mobility of U.  Electrochemical measurements further show the decrease of the U(VI) to U(V) redox potential of the uranyl–carbonato complex with decreasing pH suggesting the first electron transfer is critical determining the rate and extent of uranium reduction.